The oxychloride, bromides, and other compounds were subsequently discovered; here we need only notice Moissan's preparation of the trifluoride and Thorpe's discovery of the pentafluoride, a compound of especial note, for it volatilizes unchanged, giving a vapour of normal density and so demonstrating the stability of a pentavalent phosphorus compound (the pentachloride and pentabromide dissociate into a molecule of the halogen element and phosphorus trichoride).
This artifice is specially valuable when the substance decomposes or volatilizes in a warm current of carbon dioxide.
In the oxyhydrogen flame silver boils, forming a blue vapour, while platinum volatilizes slowly, and osmium, though infusible, very readily.
It has also been shown that gold volatilizes when a gold-amalgam is distilled.
The barium salt is extracted by water and boiled with nitric acid, when the osmium volatilizes in the form of its tetroxide.