Stas carried out such experiments on the composition of silver chloride and of ammonium chloride, but he never found a variation of one part in 10,000 in the composition of the substances.
This is also the case if two substances are brought together in solution, by the action of which upon each other a third body is formed which is insoluble in the solvent employed, and which also does not tend to react upon any of the substances present; for instance, when a solution of a chloride is added to a solution of a silver salt, insoluble silver chloride is precipitated, and almost the whole of the silver is removed from solution, even if the amount of the chloride employed be not in excess of that theoretically required.
Faraday examined also the electrolysis of certain fused salts such as lead chloride and silver chloride.
Let us consider the arrangement - silver I silver chloride with potassium chloride solution I potassium nitrate solution I silver nitrate solution I silver.
The resulting precipitate of silver chloride is filtered, and the residue and the precipitate are scorified together.