Owing to the variation in the value of the dielectric constant of glass with the temperature and with the frequency of the applied electromotive force, and also owing to electric glow discharge from the edges of the tin foil coatings, the capacity of an ordinary Leyden jar is not an absolutely fixed quantity, but its numerical value varies somewhat with the method by which it is measured, and with the other circumstances above mentioned.
It has long been known that air and other gases at the pressure of the atmosphere were very perfect insulators, but that when they were rarefied and contained in glass tubes with platinum electrodes sealed through the glass, electricity could be passed through them under sufficient electromotive force and produced a luminous appearance known as the electric glow discharge.
It is then usually partially backfilled with argon to avoid the possibility of forming a glow discharge.