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Silicon being a larger atom than carbon can form only a single covalent bond with an oxygen atom.
That allows the formation of covalent bonds between the two.
Summary At room temperature, solid aluminum chloride has an ionic lattice with a lot of covalent character.
Radicals also come together forming covalent bond in Termination steps.
An OH - nucleophile forms a dative covalent bond with one of the hydrogen atoms.
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